Effect of Isothermal Ageing on Structural and Magnetic Properties of Ni47Mn40Sn13 Ferromagnetic Shape Memory Alloy

Authors

1 1- Department of Physics, Isfahan University of Technology, Isfahan, Iran

2 2- Department of Materials Engineering, Isfahan University of Technology, Isfahan, Iran

Abstract

In this investigation, Ni47Mn40Sn13 ferromagnetic shape memory alloy was prepared by mechanical alloying. The metal powders were ball milled in argon atmosphere for 20 hours. X-ray diffraction pattern confirmed formation of crystalline structure of Heusler alloy. As-milled powder samples were sealed in quartz tubes under high vacuum and subjected to heat treatments at 950°C for different time durations. Then, the effect of isothermal ageing on structural, magnetic and electrical properties of samples was investigated. Results of electrical resistance displayed a metal-like behavior around martensitic transformation. The results showed that 16 hours of annealing was the optimal time for producing this alloy which could be an appropriate candidate for magnetic refrigerant.

Keywords


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Vol. 21, pp. 233201-233230, 2009.
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4. Ghotbi Varzaneh, A., Kameli, P., Karimzadeh, F., Aslibeiki, B., Varvaro, G. and Salamati, H., \"Magnetocaloric Effect in Ni47Mn40Sn13 Alloy Prepared by Mechanical Alloying\", Journal of Alloys and Compounds, Vol. 598, pp. 6-10, 2014.
5. Dincer, I., Yüzüak, E. and Elerman, Y., \"Influence of Irreversibility on Inverse Magnetocaloric and Magnetoresistance Properties of the (Ni, Cu)50Mn36Sn14 Alloys\", Journal of Alloys and Compounds, Vol. 506, pp. 508-512, 2010.
6. زاهدی، و.، \"بررسی خواص ساختاری و مغناطیسی آلیاژ حافظه‌پذیر فرو مغناطیس Ni50Mn50-xInx\"، پایان نامه کارشناسی ارشد، دانشگاه صنعتی اصفهان، اصفهان، 1391.
7. Muthu, S.E., Rao, N.R., Raja, M.M., Kumar, D.R., Radheep, D.M. and Arumugam, S., \"Influence of Ni/Mn Concentration on the Structural, Magnetic and Magnetocaloric Properties in Ni50−xMn37+xSn13 Heusler Alloys\", Journal of Physics D: Applied Physics, Vol. 43, p. 425002-425007, 2010.
8. Hakimi, M., Kameli, P. and Salamati, H., \"Structural and Magnetic Properties of Co2CrAl Heusler Alloys Prepared by Mechanical Alloying\", Journal of Magnetism and Magnetic Materials, Vol. 322,
pp. 3443-3446, 2010.
9. Ren, Z., Li, S. and Luo, H., \"Structure and Magnetic Properties of Fe2CoGe Synthesized by Ball-Milling\", Physica B: Condensed Matter, Vol. 405, pp. 2840-2843, 2010.
10. Zhao, X., Hsieh, C., Lai, J., Cheng, X., Chang, W., Cui, W., Liu, W. and Zhang, Z., \"Effects of Annealing on the Magnetic Entropy Change and Exchange Bias Behavior in Melt-Spun Ni–Mn–In ribbons\", Scripta Materialia, Vol. 6, pp. 250-253, 2010.
11. Wang, Y., Ren, Y., Nie, Z., Liu, D., Zuo, L., Choo, H., Li, H., Liaw, P., Yan, J. and McQueeney, R.J., \"Structural Transition of Ferromagnetic Ni2MnGa Nanoparticles\", Journal of Applied Physics, Vol. 101, pp. 063530-063536, 2007.
12. Han, Z., Chen, X., Zhang, Y., Chen, J., Qian, B., Jiang, X., Wang, D. and Du, Y., \"Martensitic Transformation and Magnetocaloric Effect in Mn–Ni–Nb–Sn Shape Memory Alloys: The effect of 4d transition-metal doping\", Journal of Alloys and Compounds, Vol. 515, pp. 114-118, 2012.
13. Tian, B., Chen, F., Tong, Y., Li, L., Zheng, Y., Liu, Y. and Li, Q., \"Phase Transition of Ni–Mn–Ga Alloy Powders Prepared by Vibration Ball Milling\", Journal of Alloys and Compounds, Vol. 509,
pp. 4563-4568, 2011.
14. Chieda, Y., Kanomata, T., Fukushima, K., Matsubayashi, K., Uwatoko, Y., Kainuma, R., Oikawa, K., Ishida, K., Obara, K. and Shishido, T., \"Magnetic Properties of Mn-rich Ni2MnSn Heusler Alloys under Pressure\", Journal of Alloys and Compounds, Vol. 486, pp. 51-54, 2009.
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