Investigating the Effect of Co-Cr-Sn Ions Substitution on Microstructure and Magnetic Properties of M-type Barium Hexaferrites

Authors

1 1- Department of Engineering, Imam Hossein University, Tehran, Iran

2 2- Young Researchers and Elites club, Science and Research Branch, Islamic Azad University, Tehran, Iran

Abstract

In this research, investigation of the microstructure and magnetic properties of doped barium hexaferrite with cobalt, chromium and tin with BaCoxCrxSnxFe12-3xO19 (x=0.3,0.5) formula, was performed using solid state method. Phase and structural investigation by X-ray Diffraction (XRD) and Fourier Transform Infrared (FTIR) Spectroscopy respectively, confirmed the formation of barium hexaferrites single phase without the presence of non-magnetic secondary phase after heat treatment for 5 h at temperature of 1000 °C. Also, according to scanning electron microscopy (SEM) images, morphology of particles was perfectly hexagonal with average particle size 200-250 nm. Based on magnetic parameters measured by Vibrating Sample Magnetometer (VSM), both samples were soft magnetic and the highest saturation magnetization was obtained for the sample with composition of BaCo0.3Cr0.3Sn0.3Fe11.1O19. The values of saturation magnetization (Ms) and the coercivity (Hc) were 42.21 emu/g and 656 Oe respectively for this compound.

Keywords

References

1. Ozeri, H.S., Kucuk, I. and Zkan, H.O., "Improvement in Magnetic Properties of La Substituted BaFe12O19 Particles Prepared with an Unusually Low Fe/Ba Molar Ratio", Journal of Magnetism and Magnetic Materials, Vol. 323,
pp. 1799-1804, 2011.
2. Wang, L., Zhang, J., Zhang, Q., Xu, N. and Song, J., "XAFS and XPS Studies on Site Occupation of Sm3+ Ions in Sm Doped M-type BaFe12O19", Journal of Magnetism and Magnetic Materials, Vol. 377,
pp. 362-367, 2015.
3. Zhao, L., Lv, X., Wei, Y., Ma, C. and Zhao, L., "Hydrothermal Synthesis of Pure BaFe12O19 Hexaferrite Nanoplatelets under High Alkaline System", Journal of Magnetism and Magnetic Materials, Vol. 332, pp. 44-47, 2013.
4. Xu, X., Park, J., Hong, Y.K. and Lane, A.M., "Synthesis and Characterization of Hollow Mesoporous BaFe12O19 Spheres", Journal of Solid State Chemistry, Vol. 222, pp. 84-89, 2015.
5. Wang, Y., Huang, Y. and Wang, Q., "Preparation and Magnetic Properties of BaFe12O19/Ni0.8Zn0.2Fe2O4 Nanocomposite Ferrite", Journal of Magnetism and Magnetic Materials, Vol. 324, pp. 3024-3028, 2012.
6. Choi, M., Cho, S., Song, Y., Choi, D., Park, S. and Kim, Y., "Novel Synthesizing Method of BaFe12O19 Microrod and its Superior Coercivity with Shape Anisotropy", Materials Letters, Vol. 139, pp. 292-295, 2015.
7. Hongfei, L., Jianjiang, W., Baocai, X., Guoshun, W., Yongshen, H., Haitao, G. and Weimin, Y., "Effects of Mg or Sr Doping on the Intrinsic Characteristics and Absorption Properties of Micro-Nano BaFe12O19 Hollow Multiphase Ceramic Microspheres", Journal of Magnetism and Magnetic Materials, Vol. 374,
pp. 530-538, 2015.
8. Widanarto, W., Jandra, M., Ghoshal, S.K., Effendi, M. and Cahyanto, W.T., "BaCO3 Mediated Modifications in Structural and Magnetic Properties of Natural Nanoferrites", Journal of Physics and Chemistry of Solids, Vol. 79, pp. 78-81, 2015.
9. Molaei, M.J., Ataie, A., Raygan, S. and Picken, S.J., "Role of Intensive Milling in the Processing of Barium Ferrite/Magnetite/Iron Hybrid Magnetic Nano-Composites via Partial Reduction of Barium Ferrite", Materials Characterization, Vol. 101,
pp. 78-82, 2015.
10. Vinnik, D.A., Zherebtsov, D.A., Mashkovtseva, L.S., Nemrava, S., Semisalova, A.S., Galimov, D.M., Gudkova, S.A., Chumanov, I.V., Isaenko, L.I. andNiewa, R., "Growth, Structural and Magnetic Characterization of Co- and Ni-Substituted Barium Hexaferrite Single Crystals", Journal of Alloys and Compounds, Vol. 628, pp. 480-484, 2015.
11. Luo, J., Xu, Y. and Mao, H., "Magnetic and Microwave Absorption Properties of Rare Earth Ions (Sm3+, Er3+) Doped Strontium Ferrite and its Nanocomposites with Polypyrrole", Journal of Magnetism and Magnetic Materials, Vol. 381,
pp. 365-371, 2015.
12. Castro, W.S., Correa, R.R., Paulim Filho, P.I., Rivas Mercury, J.M. and Cabral, A.A., "Dielectric and Magnetic Characterization of Barium Hexaferrite Ceramics", Ceramics International, Vol. 41, pp. 241-246, 2015.
13. Liu, M., Yang, H., Lin, Y. and Yang, Y., "One-step Synthesis of Homogeneous BaFe12O19/Y3Fe5O12 Composite Powders", Materials Research Bulletin, Vol. 60, pp. 195-200, 2014.
14. Lisjak, D., "The Influence of Magnetic Interactions and Shape Anisotropy on the Alignment and Assembly of BaFe12O19 and Er2O3 Nanoplates", Materials Chemistry and Physics, Vol. 148, pp. 311-318, 2014.
15. Wang, Y., Huang, Y. and Ding, J., "Synthesis and Electromagnetic Absorption Properties of Polypyrrole/BaFe12O19–Ni0.8Zn0.2Fe2O4/Multi-walled carbon Nanotube Composites", Materials Science in Semiconductor Processing, Vol. 26, pp. 632-641, 2014.
16. Nabiyouni, G., Ghanbari, D., Yousofnejad, A. and Seraj, M., "A Sonochemical-Assisted Method for Synthesis of BaFe12O19 Nanoparticles and Hard Magnetic Nanocomposites", Journal of Industrial and Engineering Chemistry, Vol. 20, pp. 3425-3429, 2014.
17. Verma, S., Pandey, O.P., Paesano, A. and Sharma, P., "Comparison of Structural and Magnetic Properties of La3+ Substituted BaFe12O19 Prepared by Different Substitution Methods", Physica B: Condensed Matter, Vol. 448, pp. 57-59, 2014.
18. Kishimoto, M., Kitahata, S. and Amemiya, M., "Structural and Magnetic Properties of BaCoxFe12xO19 (x=0.2, 0.4, 0.6, 1) Nanoferrites Synthesized via Citrate Sol-Gel Method", Journal of Applied Physics, Vol. 61, pp. 101-104, 2011.
19. Xia, A., Du, D., Li, P. and Sun, Y., "Crystalline Structures and Intrinsic Magnetic Properties of ZnTi-Substituted Hexagonal M-type Ba Ferrite Powder", Journal of Materials Science Materials in Electronics., Vol. 22, pp. 223–227, 2011.
20. Kaur, T., Kaur, B., Bhat, B., Kumar, S. and Srivastava, A.K., "Effect of Calcinations Temperature on Microstructure, Dielectric, Magnetic and Optical Properties of Ba0.7La0.3Fe11.7Co0.3O19 Hexaferrites", Physica B, Vol. 456, pp. 206-212, 2015.
21. Zi, Z.F., Liu, Q.C., Dai, J.M. and Sun, Y.P., "Effects of Ce–Co Substitution on the Magnetic Properties of M-type Barium Hexaferrites", Solid State Communications, Vol. 152, pp. 894-897, 2012.
22. Choi, M., Cho, S., Song, Y., Baek, S., Kim, H., Jung, J., Lee, H., Park, C., Park, S. and kim, Y., "Synthesis and Characterization of Hollow BaFe12O19 Submicron Spheres for Advance Functional Magnetic Materials", Current Applied Physics,
Vol. 14, pp. 1208-1211, 2014.
23. Soman, V.V., Nanoti, V.M. and Kulkarni, D.K., "Effect of Substitution of Zn-Ti on Magnetic and Dielectric Properties of BaFe12O19", Physics Procedia, Vol. 54, pp. 30-37, 2014.
24. Sharma, M., Kashyap, S.C. and Gupta, H.C., "Effect of Mg–Zr Substitution and Microwave Processing on Magnetic Properties of Barium Hexaferrite", Physica B: Condensed Matter, Vol. 448, pp. 24-28, 2014.
25. Manikandan, M. and Venkateswaran, C., "Effect of High Energy Milling on the Synthesis Temperature, Magnetic and Electrical Properties of Barium Hexagonal Ferrite", Journal of Magnetism and Magnetic Materials, Vol. 358–359, pp. 82-86, 2014.
26. Zhang, M., Zi, Z., Liu, Q., Zhu, X., Liang, C., Sun, Y. and Dai, J., "Solvothermal Synthesis and Magnetic Properties of BaFe12−2x(NiTi)xO19 Nanoparticles", Journal of Magnetism and Magnetic Materials, Vol. 369, pp. 23-26, 2014.
27. Dong, C., Wang, X., Zhou, P., Liu, T., Xie, J. and Deng, L., "Microwave Magnetic and Absorption Properties of M-type Ferrite BaCoxTixFe12-2xO19 in the Ka band", Journal of Magnetism and Magnetic Materials, Vol. 354, pp. 340-344, 2014.
28. Li, J., Zhang, H., Li, Q., Li, Y. and Yu, G., "Influence of La-Co Substitution on the Structure and Magnetic Properties of Low-Temperature Sintered M-type Barium Ferrites", Journal of Rare Earths, Vol. 31, pp. 983-987, 2013.
29. El-Sayed, S.M., Meaz, T.M., Amer, M.A. and El-Shersaby, H.A., "Magnetic Behavior and Dielectric Properties of Aluminum Substituted M-Type Barium Hexaferrite", Physica B, Vol. 426, pp. 137–143, 2013.
30. Gairola, S.P., Verma, V., Singh, A., Purohit, L.P. and Kotnala, R.K., "Modified Composition of Barium Ferrite to Act as a Microwave Absorber in X-Band Frequencies", Solid State Communications, Vol. 150, pp. 147-151, 2010.
31. Ghasemi, A., Hossienpour, A., Morisako, A., Saatchi, A. and Salehi, M.," Electromagnetic Properties and Microwave Absorbing Characteristics of Doped Barium Hexaferrite", Journal of Magnetism and Magnetic Materials, Vol. 302,
pp. 429-435, 2006.
38. Jamalian, M., "An Investigation of Structural, Magnetic and Microwave Properties of Strontium Hexaferrite Nanoparticles Prepared by a Sol-gel Process with Doping Sn and Tb", Journal of Magnetism and Magnetic Materials, Vol. 378,
pp. 217-220, 2015.
39. Davoodi, A. and Hashemi, B., "Magnetic Properties of Sn-Mg Substituted Strontium Hexaferrite Nanoparticles Synthesized via Co-precipitation Method", Journal of Alloys Compound., Vol. 509, pp. 5893-5896, 2011.
40. Jamalian, M., Ghasemi, A. and Paimozd, E., "Sol-gel Synthesis of Mn-Sn-Ti Substituted Strontium Hexaferrite Nanoparticles: Structural, Magnetic and Reflection Loss Properties", Journal of Electronic Materials, Vol. 43, pp. 1076-1082, 2014.
41. Qiu, J., Gu, M. and Shen, H., "Microwave Absorption Properties of Al- and Cr-Substituted M-type Barium Hexaferrite", Journal of Magnetism and Magnetic Materials, Vol. 295, pp. 263-268, 2005.
42. Ashiq, M.N., Iqbal, M.J. and Hussain-Gul, I., "Effect of Al–Cr Doping on the Structural, Magnetic and Dielectric Properties of Strontium Hexaferrite Nanomaterials", Journal of Magnetism and Magnetic Materials, Vol. 323, pp. 259-263, 2011.
43. Awawdeh, M., Bsoul, I. and Mahmood, S.H., "Magnetic Properties and Mossbauer Spectroscopy on Ga, Al, and Cr Substituted Hexaferrites", Journal of Alloys and Compounds, Vol. 585, pp. 465-473, 2014.
44. Manafi, S. and Jafarian, M., "Synthesis of Perovskite CaTiO3 Nanopowders with Different Morphologies by Mechanical Alloying without Heat Treatment", International Journal of Physical Sciences, Vol. 8, pp. 1277-1283, 2013.
Journal of Advanced Materials in Engineering (Esteghlal)
Volume 35, Issue 3
December 2016
Pages 69-80

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