Journal of Advanced Materials in Engineering

Journal of Advanced Materials in Engineering

Synthesis and Characterization of Sintered Glass-Ceramics from Industrial Wastes for Thermal Energy Storage Systems of Concentrated Solar Power Plants

Document Type : Original Article

Author
Department of Metals, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran
Abstract
Introduction and Objectives: This study investigated the feasibility of using industrial wastes to produce glass-ceramics suitable for thermal energy storage in concentrated solar power plants. The objective was to produce glass-ceramics from three types of industrial wastes and evaluate their corrosion resistance against molten carbonate salts as the heat transfer medium at high temperatures.
Materials and Methods: For this purpose, three raw materials including blast furnace slag, ladle furnace slag, and artificial stone waste were used. The samples were sintered using a single-step method. Phase identification was performed by X-ray diffraction, and microstructure examination was conducted using scanning electron microscopy. Physical properties including density, water absorption, and Vickers hardness were measured, and specific heat capacity was determined by differential scanning calorimetry. Additionally, the samples were exposed to molten carbonate salt at 800°C for one week to evaluate their corrosion resistance.
Results: The sample derived from ladle furnace slag, with its dense structure, exhibited the highest hardness (7.9 GPa) and the lowest water absorption (0.028%). The sample derived from blast furnace slag showed the highest specific heat capacity (~ 0.8 J/g·°C). The corrosion test also indicated excellent resistance of the ladle furnace slag-derived sample, with the lowest penetration depth and surface degradation against the molten salt.
Conclusion: The glass-ceramic produced from ladle furnace slag, possessing a favourable combination of mechanical properties, physical characteristics, and corrosion resistance, is considered as a suitable and economical option in thermal energy storage systems in contact with molten carbonates.
Keywords
Subjects

1. Achkari O, El Fadar AJ. Latest developments on TES and CSP technologies–Energy and environmental issues, applications and research trends. Appl Therm Eng. 2020;167:114-806. https://doi.org/10.1016/j.applthermaleng.2019.114806
2. Fakri H, El Fadar A. TES materials integrated in CSP plants: Research trends, challenges and 3E performance analysis. Sol Energy Mater Sol Cells 2025;293:113861. https://doi.org/10.1016/j.solmat.2025.113861    
3. Mira-Hernández C, Flueckiger SM, Garimella SV. Comparative analysis of single-and dual-media thermocline tanks for thermal energy storage in concentrating solar power plants. J Sol Energy Eng. 2015;137(3):031012. https://doi.org/10.1115/1.4029453
4. Hrifech S, Agalit H, Jarni A, Mouguina EM, Grosu Y, Faik A, et al. Characterization of natural rocks as filler materials for medium-temperature packed bed thermal energy storage system. J Energy Storage 2020;32:101822. https://doi.org/10.1016/j.est.2020.101822
5. Xu B, Han J, Kumar A, Li P, Yang Y. Thermal storage using sand saturated by thermal-conductive fluid and comparison with the use of concrete. J Energy Storage 2017;13:85-95. https://doi.org/10.1016/j.est.2017.06.010
6. Caramitu AR, Lungu MV. An overview of thermal energy storage (TES) materials and systems for storage applications. Electroteh Electron Autom. 2024;72(4). https://doi.org/10.46904/eea.24.72.4.1108003
7. Wang Y, Wang Y, Li H, Zhou J, Cen K. Thermal properties and friction behaviors of slag as energy storage material in concentrate solar power plants. Sol Energy Mater Sol Cells 2018;182:21-9. https://doi.org/10.1016/j.solmat.2018.03.020
8. Agalit H, Zari N, Maaroufi M. Thermophysical and chemical characterization of induction furnace slags for high temperature thermal energy storage in solar power plants. Sol Energy Mater Sol Cells 2017;172:168-76. https://doi.org/10.1016/j.solmat.2017.07.035
9. Enemuo M, Enemuo N, Taleghani AD, Ogunmodimu O. Slags as thermal energy storage media for concentrated solar power and renewable energy integration. Energy Storage 2025;7(8):e70274. https://doi.org/10.1002/est2.70274
10. Zou J, Liu Z, Guo Q. Comprehensive utilisation of blast furnace slag. Can Metall Q. 2024;63(3):927-34. https://doi.org/10.1080/00084433.2023.2235147
11. Zhao S, Liu B, Ding Y, Zhang J, Wen Q, Ekberg C, et al. Study on glass-ceramics made from MSWI fly ash, pickling sludge and waste glass by one-step process. J Clean Prod. 2020;271:122674. https://doi.org/10.1016/j.jclepro.2020.122674
12. Rawlings RD, Wu JP, Boccaccini AR. Glass-ceramics: their production from wastes—a review. J Mater Sci. 2006;41(3):733-61. https://doi.org/10.1007/s10853-006-6554-3
13. Wang C, Jia H, Wang A, Wang X, Guo Y, Zhang J. Effect of TiO2 on the crystallization and properties of MgO-Al2O3-SiO2 glass-ceramics prepared by an "one-step" method from laterite ore. Ceram Int. 2019;45(4):5133-8. https://doi.org/10.1016/j.ceramint.2018.10.051
14. Shearer A, Montazerian M, Deng B, Sly JJ, Mauro JC. Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase. Int J Ceram Eng Sci. 2024;6(2):e10200. https://doi.org/10.1002/ces2.10200
15. Gali S, Arjun A, Premkumar HB. Zirconia toughened fluorosilicate glass-ceramics for dental prosthetic restorations. Mater Chem Phys. 2024;324:129703. https://doi.org/10.1016/j.matchemphys.2024.129703
16. Luo Y, Wang F, Liao Q, Liu L, Wang Y, Zhou J, et al. Effect of TiO2 on crystallization kinetics, microstructure and properties of building glass-ceramics based on granite tailings. J Non Cryst Solids 2021;572:121092. https://doi.org/10.1016/j.jnoncrysol.2021.121092
17. Canikoğlu N, Özarslan C, Toplan HÖ. Investigation of Li2O and TiO2 effects on MAS glass-ceramic produced from waste material. Sci Sinter. 2023;55(2). https://doi.org/10.2298/SOS220617008C
18. Zhang S, Zhang Y, Qu Z. Effects of soluble Cr2O3 doping on the glass structure, microstructure, crystallization behavior, and properties of MgO–Al2O3–SiO2 sapphirine glass ceramics. Mater Chem Phys. 2020;252:123115. https://doi.org/10.1016/j.matchemphys.2020.123115 
19. Yu J, Peng Z, Shang W, Chen Q, Zhu G, Tang H, et al. Dual roles of Cr2O3 in preparation of glass-ceramics from ferronickel slag. Ceram Int. 2023;49(10):15947-58. https://doi.org/10.1016/j.ceramint.2023.01.191
20. Alzahrani JS, Echeweozo EO, Alrowaili ZA, Sriwunkum C, Kırkbınar M, Çaliskan F, et al. Influence of Fe2O3 on synthesis, structure, hardness, and radiation shielding properties of Apatite–Wollastonite (AW) glass ceramics for bone implantation and shielding applications. Ceram Int. 2024;50(18):32884-92. https://doi.org/10.1016/j.ceramint.2024.06.099 
21. Zhang S, Zhang Y, Wu S. Effects of ZnO, FeO and Fe2O3 on the spinel formation, microstructure and physicochemical properties of augite-based glass ceramics. Int J Miner Metall Mater. 2023;30(6):1207-16. https://doi.org/10.1007/s12613-022-2489-1
22. Muniz RF, Soares VO, Montagnini GH, Medina AN, Baesso ML. Thermal, optical and structural properties of relatively depolymerized sodium calcium silicate glass and glass-ceramic containing CaF2. Ceram Int. 2021;47(17):24966-72. https://doi.org/10.1016/j.ceramint.2021.05.224
23. Karamanov A, Hamzawy EM, Karamanova E, Jordanov NB, Darwish H. Sintered glass-ceramics and foams by metallurgical slag with addition of CaF2. Ceram Int. 2020;46(5):6507-16. https://doi.org/10.1016/j.ceramint.2019.11.132
24. Zhu C, Jiao LX, Xi XM, Li BR. Influences of the SiO2-Al2O3 mixture on phase evolution and properties of steel slag-based glass ceramic used for thermal energy storage. Ceram Int. 2025;51(19):27578-91. https://doi.org/10.1016/j.ceramint.2025.03.431
25. Song J, Luo F, Chen G. A new photoelectric niobate glass ceramic material: Up-conversion optical thermometry and dielectric energy storage. Ceram Int.  2023;49(16):27266-76. https://doi.org/10.1016/j.ceramint.2023.05.281
26. Jiao LX, Zhu C, Zhang SG, Li WH, Yang L, Wu YY, et al. High temperature corrosion behavior and mechanism of steel slag-based glass ceramic in the eutectic carbonates. Ceram Int. 2024;50(20):39951-64. https://doi.org/10.1016/j.ceramint.2024.07.378
27. Liu H, Lu H, Chen D, Wang H, Xu H, Zhang R. Preparation and properties of glass–ceramics derived from blast-furnace slag by a ceramic-sintering process. Ceram Int. 2009;35(8):3181-4. https://doi.org/10.1016/j.ceramint.2009.05.001
28. Zhang W, He F, Xiao Y, Xie M, Li F, Xie J, et al. Structure, viscosity, and crystallization of glass melt from molten blast furnace slag. Int J Appl Glass Sci. 2020;11(4):676-84. https://doi.org/10.1111/ijag.15054
29. Shang W, Peng Z, Huang Y, Gu F, Zhang J, Tang H, et al. Production of glass-ceramics from metallurgical slags. J Clean Prod. 2021;317:128220. https://doi.org/10.1016/j.jclepro.2021.128220
30. Han L, Du R, Dong L, Chen Y, Xi C, Mei N, et al. Recycling of waste granite and glass powder for the preparation of architectural glass-ceramic. J Mater Res Technol. 2025;39: 3556-3565. https://doi.org/10.1016/j.jmrt.2025.10.003
31. Xie CS, Gui YL, Song CY, Hu BS. Effect of CaO/SiO2 and heat treatment on the microstructure of glass-ceramics from blast furnace slag. Ceram - Silik. 2016;60:146-51. https://doi.org/10.13168/cs.2016.0022
32. Chen CH, Feng KQ, Zhou Y, Zhou HL. Effect of sintering temperature on the microstructure and properties of foamed glass-ceramics prepared from high-titanium blast furnace slag and waste glass. Int J Miner Metall Mater. 2017;24(8):931-6. https://doi.org/10.1007/s12613-017-1480-8
33. Karamanov A, Pelino M. Induced crystallization porosity and properties of sintereds diopside and wollastonite glass-ceramics. J Eur Ceram Soc. 2008;28(3):555-62. https://doi.org/10.1016/j.jeurceramsoc.2007.08.001
34. Zhang Z, Ma H, Wu C, Sun Y, Chen R, Guo X. Properties of glass-ceramics prepared from industrial multi-wastes. Separations 2023;10(9):498. https://doi.org/10.3390/separations10090498
35. Almasri KA, Matori KA, Zaid MH. Effect of sintering temperature on physical, structural and optical properties of wollastonite based glass-ceramic derived from waste soda lime silica glasses. Results Phys. 2017;7:2242-7. https://doi.org/10.1016/j.rinp.2017.04.022
36. Miró L, Navarro ME, Suresh P, Gil A, Fernández AI, Cabeza LF. Experimental characterization of a solid industrial by-product as material for high temperature sensible thermal energy storage (TES). Appl Energy 2014;113:1261-8. https://doi.org/10.1016/j.apenergy.2013.08.082
37. Majó M, Calderón A, Salgado-Pizarro R, Svodobova-Sedlackova A, Barreneche C, Chimenos JM, et al. Assessment of solid wastes and by‐products as solid particle materials for concentrated solar power plants. Solar RRL 2022;6(6):2100884. https://doi.org/10.1002/solr.202100884
38. Sarkar S. Solid waste management in steel industry-challenges and opportunities. Int J Econ Manag Eng. 2015; 9(3): 987-981. 
39. Muñoz I, Soto A, Maza D, Bayon F. Life cycle assessment of refractory waste management in a Spanish steel works. Waste Manage. 2020;111:1-9. https://doi.org/10.1016/j.wasman.2020.05.023
40. Gurtubay L, Gallastegui G, Elias A, Rojo N, Barona A. Accelerated ageing of an EAF black slag by carbonation and percolation for long-term behaviour assessment. J Environ Manage. 2014;140:45-50. https://doi.org/10.1016/j.jenvman.2014.03.011 
 
 

تحت نظارت وف بومی