Evaluation of Synthesizing Al2O3 Nano Particles in Copper Matrix by Mechanical Alloying of Cu-1% Al and Copper Oxide

Authors

Department of Materials Science and Engineerig, Shahid Bahonar, Kerman, Iran

Abstract

Strengthening of copper matrix by dispersion of metallic oxides particles as an efficient way to increase strength without losing thermal and electrical conductivities has been recognized for many years. Such a composite can withstand high temperatures and keep its properties. Such copper alloys have many applications especially in high temperature including resistance welding electrodes, electrical motors and switches. In the present work, at first, the Cu-1%Al solid solution was prepared by the mechanical alloying process via 48 hours of milling. Subsequently, 0.66 gr of copper oxide was added to Cu-1%Al solid solution and mechanically milled for different milling times of 0,16, 32, 48 hours. The milled powder mixtures were investigated by X-Ray Diffraction and scanning electron microscopy techniques. The lattice parameter of Cu increased at first, but then decreased at longer milling times. The internal strain increased and the average Cu crystal size decreased during milling process.The particle size decreased during the whole process. With increasing annealing temprature from 450°C to 750°C, the microhardness values of samples decreased at the beginning but then increased. From these results, it can be concluded that nanosize aluminaparticles are formed in the copper matrix.

Keywords


1. ASM International Handbook Committee, Metals Handbook, ,” Properties and Selection: Nonferrous Alloys and Special-Porpouse Materials”, Metals park, ohio, Vol. 2, pp. 217, 280-281, 1993.
2. Lopez, M., Corredor, D., and Raman, K., “Performance of new Dispersion-Precipitation Strengthened Copper-Ceramic Materials Made by Mechanical Alloying Method”, Physica Status Solidi, pp. 4248-4253, 2007.
3. Rajkovic, V., Bozic, D., Devecerski, A., and Jovavic, M. T., “Characteristics of Copper Matrix Reinforced with Nano and Micro-Sized Al2O3 Particles”, Materials Characterization, Vol. 67, pp.129-137, 2012.
4. Rajcovic, V., Bozic, D., and Jovnovic, M. T., “Effects of Copper and Al2O3 Particles on Characteristics of Cu–Al2O3 Composites”, Mateials and Design, Vol. 31, pp. 1962-1970, 2010.
5. Schaffer, G. B., and McCormick, P. G,“Reduction of Tantalum Chloride by Magnesium During Reaction Milling”, Meterial Transition, Vol. 22A, pp.3019-3024, 1991.
6. Zhang, D. L., and Richmond, J. R., J.,“Processing of Cu-Al2O3 Metal Matrix Nanocomposite Materials”. Material Science, Vol. 34, pp.701, 1999.
7. Cao, G, Synthesis, Properties and Applications Nanostructures and Nanomaterials, Imperial College Press, London, 2004.
8. Schaffer, G. B., and McCormick, P. G., “Anomalous Combustion Effects During Mechanical Alloying”, Metallurgical and Materials Transactions A, Vol. 22, No. 12, pp. 3019-3024,1991.
9. Zhang, D. L., and Richmond, J. R., “Microstructural Evolution During Combustion Reaction between CuO and Al Induced by High Energy Ball Milling”, Journal. of Materials Science, Vol. 34, pp. 701-706, 1991.
10. Zhung, Z, and Chen, L. D., “Consideration of Orowan Strengthening Effect in Particulate-Reinforced Metal Matrix Nanocomposites A Model for Predicting their Yield Strength”. Scripta Mater, Vol. 54, pp.1321-1326, 2006.
11. Korac, M., Kamberovic, Z., Andjic, Z., Filipovic, M., and Tasic, M., “Sintered Materials Based on Copper and Alumina Powders Synthesized by a Novel Method”, Science of Sintering, Vol. 42, pp. 81-90, 2010.
12. Nadkarani, A., Copper and Copper Alloys. In:ASM handbook, vol. 7. Metals Park (OH): ASM International, pp. 869-873, 1990.
13. Valdiviez, R., Schrage, D., Martinez, F., and Clark, W., “The Use of the Dispersion Strengthened Copper in Accelerator Design”, Processing of the 20th international Linac conference, Monterey (CA), pp. 956-958, 2000.
14. Motta, S. M., Jena, K. P., Brocchi, A. E., and Solorzano, G. I., “Characterization of Cu-Al2O3 Nano-Scale Composites Synthesized by in Situ Redution”, Material Science Engineering, C(15), pp. 175-177, 2001.
15. Groza, J. R., and Gibeling, J. C., “Principles of Particle Selection for Dispersion-Strengthened Copper”, Material Science and Engineering. A171, pp. 115-125, 1993.
17. Jianyi, C., Mingpu, W., and Yanhui, L. Z. W., “Nano-Scale Al2O3 Dispersion-Strengthened Copper Alloy Produced by Internal Oxidation”, In: China-EU Forum on Nanosized Technology, Beijing, P.R. China, pp. 93-101, 2002.
18. Tiang, B., Liu, P., Song, K., Li, Y., and Ren, F., “Microstructure and Properties at Elevated Temperature of Nano-Al2O3 Particles Dispersion-Strengthened Copper Base Composite”, Material Science Engineering, Vol. 435-436, pp. 705-710, 2006.
19. Rajkovic, M. V., and Mitkov, V. M., “Dispersion Hardened Cu-Al2O3 Produced by High-Energy Milling”, International. Journal of Powder Metallurgy, Vol. 36, pp. 45-49, 2000.
20. Lee, W. D., Ha, H. G, and Kim K. B., “Synthesis of Cu-Al2O3 Nano Composite Powder”, Scripta Material, Vol. 44, pp. 2137-2140, 2001.
21. Mobasherpour, I., Tofigh, A. A., and Ebrahimi M., “Effect of Nano-Size Al2O3 Reinforcement on the Mechanical Behavior of Synthesis 7075 Aluminum Alloy Composites by Mechanical Alloying”, Materials Chemistry and Physics, Vol. 138, pp. 535-541, 2013.
22. Azimi, A., Shokuhfar, A., and Zolriasatein, A. “Nanostructured Al-Zn-Mg-Cu-Zr Alloy Prepared by Mechanical Alloying Followed by Hot Pressing”, Materials Science & Engineering A, Vol. 595, pp.124-130, 2014.
23. Youssef, K. M., Scattergood, R. Q., Murty, K. L., Kock, C. C., “Nanocrystalline Al–Mg Alloy with Ultrahigh Strength and Good Ductility”, Scripta Material Vol. 54, pp. 251-256, 2006.
24. Rajcovice, V., Bozic, D., A. Devecerski, A., and Jovanovic, M. T., “Characteristic of Copper Matrix Simultaneously Reinforced with Nano and Micro-Sized Al2O3 Particles”, materials characterization, Vol. 67, pp. 129-137, 2012.
25. Williamson, G. K., and Hall, W. H.,“X-Ray Line Broadening from Filed Aluminium and Wolfram”, acta metallurgica, Vol. 1, pp. 22-31, 1953.
26. L. Takacs, Ball Milling-Induced Combustion in Powder Mixtures Containing, In Processing and Properties of Nanocrystalline Materials, C. Suryanarayana, Ed., pp. 453-464, TMS, Warrendale, Pa, USA, 1996.
27. Takacs, L., and Pardavi-Horvath, M. J., “Nanocomposite Formation in the Fe3o4‐zn System by Reaction Milling”, Journal of Applied Physics, Vol. 75, pp. 5864-5866, 1994.
28. Gavroliv, D., Vinogradov, O., and Shaw, W. J. D., In: A. Poursartip, K. Street, eds, 10th Processing International Conference. on Composite Materials, pp. 11, 1995.
30. Suryanarayana, C., International Journal of Non-eqilibrium Processing, Vol. 11, The University of Virginia pp. 325-345, 2002.
31. Rajkovic, V., Bozic, D., and Jovanovic, M. T., “Effects of Copper and Al2O3 Particles on Characteristics of Cu-Al2O3 Composites”, Materials and Design, Vol. 31, pp. 1962-1970, 2010.
32. Rajkovic, V., Bozic, D., and Jovanovic, M. T., “Properties of Copper Matrix Reinforced with Various Size and Amount of Al2O3 Particles”, Journal of Materials Processing Technology, Vol. 200, pp.106-114, 2008.

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