THE EFFECT OF DY- DOPING ON THE STRUCTURAL AND MAGNETIC PROPERTIES OF MN-ZN FERRITE NANOPARTICLES

Authors

Department of Mining and Metallurgical Engineering, Yazd University

Abstract

Mn0.8Zn0.2Fe2-xDyxO4 (where x= 0, 0.025, 0.05, 0.075, 0.1) ferrite nanoparticles were synthesized by auto- combustion sol-gel method for the first time in this study. The effect of Dy-doping on the structural and magnetic properties of the produced specimens was examined using the X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), vibrating sample magnetometery (VSM), and field emission scanning electron microscope (FE-SEM). The results showed that a cubic spinel structure was formed in all of the synthesized specimens. It was also found that the addition of Dy increased the lattice parameter while decreased the average of crystallites size. Furthermore, the FE-SEM micrographs showed that Dy not only plays an effective role in reducing the agglomeration of nanoparticles and their distribution, but also reduces the average of particle size. It was also observed that the addition of Dy had no effect on the morphology of the synthesized nanoparticles. Investigation of the magnetic properties revealed a clear decrease in the saturation magnetization and coercivity by the Dy addition. So that the saturation magnetization of the samples decreased from 66.3 to 58.4 emu/g and the coercivity decreased from 78.5 to 71.9 Oe.

Keywords


1. Costa, A., Silva, V. J., Xin, C. C., Vieira, D. A., Cornejo, D. R., and Kiminami, R., “Effect of Urea and Glycine Fuels on the Combustion Reaction Synthesis of Mn–Zn Ferrites: Evaluation of Morphology and Magnetic Properties”, Journal of Alloys and Compounds, Vol. 495, pp. 503-505, 2010.
2. Kalarus, J., Kogias, G., Holz, D., and Zaspalis, V. T., “High Permeability-High Frequency Stable Mn-Zn Ferrites”, Journal of Magnetism and Magnetic Materials, Vol. 324, pp. 2788-2794, 2012.
3. Kumar, A. R., Kumar, R., Chakra, C. S., and Rao, K. V., “Silver Doped Manganese-Zinc Ferrite Nano Flowers for Biomedical Applications”, International Journal of Emerging Technology and Advanced Engineering, Vol. 5, pp. 2250-2459, 2014.
4. Kumar, E. R., Reddy, P. S. P., Devi, G. S., and Sathiyaraj, S., “Structural, Dielectric and Gas Sensing Behavior of Mn Substituted Spinel MFe2O4 (M= Zn, Cu, Ni, and Co) Ferrite Nanoparticles”, Journal of Magnetism and Magnetic Materials, Vol. 398, pp. 281-288, 2016.
5. Waqas, H., Qureshi, A. H., and Shahzad, M., “Effect of Firing Temperature on the Electromagnetic Properties of Electronic Transformer Cores Developed by Using Nanosized Mn-Zn Ferrite Powders”, Acta Metallurgica Sinica (English Letters), Vol. 28, pp. 159-163, 2015.
6. Pardavi-Horvath, M., “Microwave Applications of Soft ferrites”, Journal of Magnetism and Magnetic Materials, Vol. 215, pp. 171-183, 2000.
7. Tsakaloudi, V., and Zaspalis, V. T., “A new Mn-Zn Ferrite for High-Speed Data Transmission Applications in Telecommunication Networks”, Journal of Magnetism and Magnetic Materials, Vol. 310, pp. 2540-2542, 2007.
8. Li, J., Yuan, H., Li, G., Liu, Y., and Leng, J., “Cation Distribution Dependence of Magnetic Properties of Sol-Gel Prepared MnFe2O4 Spinel Ferrite Nanoparticles”, Journal of Magnetism and Magnetic Materials, Vol. 322, pp. 3396-3400, 2010.
9. Ahmed, M. A., Rady, K. E., and Shams, M. S., “Enhancement of Electric and Magnetic Properties of Mn–Zn Ferrite by Ni–Ti Ions Substitution”, Journal of Alloys and Compounds, Vol. 622, pp. 269-275, 2015.
10. Maksoud, M. I. A., El-Sayyad, G. S., Abokhadra, A., Soliman, L. I., El-Bahnasawy, H. H., and Ashour, A. H., “Influence of Mg2+ Substitution on Structural, Optical, Magnetic, and Antimicrobial Properties of Mn–Zn Ferrite Nanoparticles”, Journal of Materials Science: Materials in Electronics, Vol. 31, pp. 2598-2616, 2020.
11. Torkian, S., Ghasemi, A., and Razavi, R. S., “Structural and Magnetic Consequences of Mn0.6Zn0.4Fe2−xGdxO4 Ferrite”, Journal of Superconductivity and Novel Magnetism, Vol. 29, pp. 1617-1625, 2016.
12. Gu, Y., Tan, X., Liang, S., and Sang, S., “Effects of La3+ Doping on Mn-Zn Ferrite Nanoscale Particles Synthesized by Hydrothermal Method”, Journal of Central South University of Technology, Vol. 11, pp. 166-168, 2004.
13. Thakur, P., Sharma, R., Kumar, M., Katyal, S., Barman, P., and Sharma, V., “Structural, Morphological, Magnetic and Optical Study of Co-Precipitated Nd3+ Doped Mn-Zn Ferrite Nanoparticles”, Journal of Magnetism and Magnetic Materials, Vol. 479, pp. 317-325, 2019.
14. Ateia, E., Ahmed, M. A., and El-Aziz, A. K., “Effect of Rare Earth Radius and Concentration on the Structural and Transport Properties of Doped Mn-Zn Ferrite”, Journal of Magnetism and Magnetic Materials, Vol. 311, pp. 545-554, 2007.
15. Ibrahim, E. M. M., “Effect of Dy+ 3 on the Structure and Static Magnetic Properties of Spin-Glass Mn-Zn Ferrite Nanoparticles”, Journal of Applied Physics, Vol. 113, pp. 154301-154306, 2013.
16. Zipare, K. V., Bandgar, S. S., and Shahane, G. S., “Effect of Dy-Substitution on Structural and Magnetic Properties of Mn-Zn Ferrite Nanoparticles”, Journal of Rare Earts, Vol. 36, pp. 86-94, 2018.
17. Sattar, A. A., Samy, A. M., ElEzza, R. S., and Eatah, A. E., “Effect of Rare Earth Substitution on Magnetic and Electrical Properties of Mn-Zn Ferrites”, Physica Status Solidi, Vol. 193, pp. 86-93, 2002.
18. Yusmar, A., Armitasari, L., and Suharyadi, E., “Effect of Zn on Dielectric Properties of Mn-Zn Spinel Ferrite Synthesized by Coprecipitation”, Materials Today Proceedings, Vol. 5, pp. 14955-14959, 2018.
19. Wang, W., Zang, C., and Jiao, Q., “Synthesis, Structure and Electromagnetic Properties of Mn-Zn Ferrite by Sol–Gel Combustion Technique”, Journal of Magnetism and Magnetic Materials, Vol. 349, pp. 116-120, 2014.
20. Li, M., Liu, X., Xu, T., Nie, Y., Li, H., and Zhang, C., “Synthesis and Characterization of Nanosized MnZn Ferrites via a Modified Hydrothermal Method”, Journal of Magnetism and Magnetic Materials, Vol. 439, pp. 228-235, 2017.
21. Imanipour, P., Hasani, S., Seifoddini, A., Farnia, A., Karimabadi, F., Jahanbani-Ardakani, K., and Davar, F., “The Possibility of Vanadium Substitution on Co lattice Sites in CoFe2O4 Synthesized by Sol-Gel Autocombustion Method”, Journal of Sol-Gel Science and Technology, Vol. 95, pp. 157-167, 2020.
22. Smilgies, D. M., “Scherrer Grain-Size Analysis Adapted to Grazing-Incidence Scattering With Area Detectors”, Journal of Applied Crystallography, Vol. 42, pp. 1030-1034, 2009.
23. Ghasemi, A., Loghman Estarki, M. R., Torkian, S., and Gordani, G. R., “Effect of Neodymium Dopping on Morphology, Phase and Magnetic Properties of Ni0.7Zn0.3NdxFe2-XO4 Ferrite Nanoparticles Synthesized By Complexing Sol-Gel Method”, Journal of Advanced Materials in Engineering, Vol. 39, No. 2, pp 121-136, 2020.
24. Hashemi, S. M., Hasani, S., Jahanbani-Ardakani, K., and Davar, F., “The Effect of Simultaneous Addition of Ethylene Glycol and Agarose on the Structural and Magnetic Properties of CoFe2O4 Nanoparticles Prepared by the Sol-Gel Auto-Combustion Method”, Journal of Magnetism and Magnetic Materials, Vol. 492, pp. 165714-165721, 2019.
25. Imanipour, P., Hasani, S. Afshari, M. , Sheykh, S., Seifoddini, A., and Jahanbani-Ardakani, K. , “The Effect of Divalent Iions of Zinc and Strontium Substitution on the Structural and Magnetic Properties on the Cobalt Site in Cobalt Ferrite”, Journal of Magnetism and Magnetic Materials, Vol. 510, pp. 166941-166952, 2020.
26. Karimi, Z., Abbasi, S., Shokrollahi, H., Yousefi, G., Fahham, M., Karimi, L., and Firuzi, O.,“Pegylated and Amphiphilic Chitosan Coated Manganese Ferrite Nanoparticles for pH-Sensitive Delivery of Methotrexate: Synthesis and Characterization”, Materials Science and Engineering: C, Vol. 71, pp. 504-511, 2017.
27. Nigam, A., and Pawar, S. J., “Structural, Magnetic, and Antimicrobial Properties of Zinc Doped Magnesium Ferrite for Drug Delivery Applications”, Ceramics International, Vol. 46, pp. 4058-4064, 2020.
28. Zargar, T., and Kermanpur, A., “Effects of Hydrothermal Process Parameters on the Physical, Magnetic and Thermal Properties of Zn03Fe2.7O4 Nanoparticles for Magnetic Hyperthermia Applications”, Ceramics International, Vol. 43, pp. 5794-5804, 2017.
29. Ansari, M., Bigham, A., Hassanzadeh Tabrizi, S. A., and Abbastabar Ahangar, H., “Copper‐Substituted Spinel Zn‐Mg Ferrite Nanoparticles as Potential Heating Agents for Hyperthermia”, Journal of the American Ceramic Society, Vol. 101, pp. 3649-3661, 2018.
30. Dhumal, J., Phadatare, M., Deshmukh, S. G., and Shahane, G. S., “Enhanced Heating Ability of Fe-Mn-Gd Ferrite Nanoparticles for Magnetic Fluid Hyperthermia”, Journal of Materials Science: Materials in Electronics, Vol. 31, pp. 11457-11469, 2020.

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