Effect of Magnetic Field and Electrospray Combination on the Orientation of Carbon Nanotubes in Alginate Core-Shell Composite Adsorbent and Methylene Blue Adsorption

Document Type : Original Article

Authors

1 Department of Nanotechnology, University of Sistan and Baluchestan, Zahedan, Iran

2 1- Department of Chemical Engineering, University of Sistan and Baluchestan, Zahedan, Iran 2- Innovation Center of Membrane Technology (ICMT), University of Sistan and Baluchestan, Zahedan, Iran

3 Department of Materials Engineering, University of Sistan and Baluchestan, Zahedan, Iran

4 1- Innovation Center of Membrane Technology (ICMT), University of Sistan and Baluchestan, Zahedan, Iran 2- Department of Chemical Engineering, University of Ardakan, Ardakan, Iran

Abstract

In the present study, the effect of magnetic field and electrospray on the orientation of carbon nanotubes (CNT), stabilized with COOH, in the obtained alginate/CNT adsorbent’s matrix, as well as the adsorption of methylene blue, were investigated. FE-SEM and UV-visible spectroscopy were used to determine the characteristics and performance of absorbents. The images showed that the CNTs were significantly oriented in the polymer matrix by placing alginate-CNTs colloid in a magnetic field with an average strength of 318 mT for 2 h. While the spraying of colloidal droplets under the electric field had a negligible effect on the alignment of CNTs, it led to the size reduction of the droplets and an increase in the specific surface area of particles. By combining magnetic and electric fields in the presence of CNT, 92.2% of the methylene blue adsorption was obtained, which was higher than electrospray only (71%), and electrospray only without CNTs (59%). This research revealed that the orientation of carbon nanotubes under magnetic and electric fields was effective in increasing the adsorption efficiency of environmental pollutants and can lead to the production of more economical adsorbents.

Keywords

Main Subjects

References

  1. Matias CA, Vilela PB, Becegato VA, Paulino AT. Adsorption and Removal of Methylene Blue from Aqueous Solution Using Sterile Bract of Araucaria angustifolia as Novel Natural Adsorbent. Int J Environ Res 2019; 13:991-1003.
  2. Papegowda PK, Syed AA. Kinetic and Thermodynamic Studies on the Removal of Methylene Blue Dye from Aqueous Solution Using Saw Palmetto Spent. Int J Environ Res 2017; 11:91-98.
  3. Vega-Negron AL, Alamo-Nole L, Perales-Perez O. Simultaneous Adsorption of Cationic and Anionic Dyes by Chitosan/Cellulose Beads for Wastewaters Treatment. Int J Env Res 2018; 12:59-65.
  4. Mohapatra L, Cheon D, Yoo SH. Carbon-Based Nanomaterials for Catalytic Wastewater Treatment: A Review. Molecules 2023; 28(4):1805.
  5. Kalantari Sh, Amini M, Shokufar A. Synthesis, characterization and application of mesoporous silica/maghemite nanocomposite in removal of heavy metal ions from aqueous solution. J Sci Technol Compos 2020; 7(3):1013-1020, (In Persian).
  6. Kong D, Zheng X, Tao Y, Lv W, Gao Y, Zhi L, Yang QH. Porous graphene oxide-based carbon artefact with high capacity for methylene blue adsorption. Adsorption 2016; 22(8):1043-1050.
  7. Phasuk A, Srisantitham S, Tuntulani T, Anutrasakda W. Facile synthesis of magnetic hydroxyapatite-supported nickel oxide nanocomposite and its dye adsorption characteristics. Adsorption 2018; 24(2):157-167.
  8. Marandi GB, Kermani ZP, Kurdtabar M. Synthesis of Collagen-Based Hydrogel Nanocomposites Using Montmorillonite and Study of Adsorption Behavior of Cd from Aqueous Solutions. Iranian J Polym Sci Technol 2013; 26(1):73-82, (In Persian).
  9. Eslami-Farsani R. Shahrabi-Farahani A. Khosravi H, Zamani MR. A study on the flexural response of grid composites containing multi-walled carbon J Sci Technol Compos 2017; 4(1):101-108, (In Persian).
  10. Khosravi H, Eslami-Farsani R, Ebrahimnezhad-Khaljiri H. An experimental study on mechanical properties of epoxy/basalt/carbon nanotube composites under tensile and flexural loadings. J Sci Technol Compos 2016; 3(2):187-194, (In Persian).
  11. Gayathri V, Geetha R. Hydrogen adsorption in defected carbon nanotubes. Adsorption 2007; 13(1):53-59.
  12. Podkościelny P, Dąbrowski A. Adsorption of phenol from aqueous solutions on original and oxidized multiwalled carbon nanotubes. Adsorp Sci Technol 2017; 35(9-10):806-816.
  13. Muhammad S, Yahya EB, Abdul Khalil HP, Marwan M, Albadn YM. Recent advances in carbon and activated carbon nanostructured aerogels prepared from agricultural wastes for wastewater treatment applications. Agriculture 2023; 13(1):208.
  14. Fiyadh SS, AlSaadi MA, Jaafar WZ, AlOmar MK, Fayaed SS, Mohd, NS, Hin LS, El-Shafie A. Review on heavy metal adsorption processes by carbon nanotubes. J Clean Product 2019; 230:783-793.
  15. Ali S, Rehman SAU, Luan HY, Farid MU, Huang H. Challenges and opportunities in functional carbon nanotubes for membrane-based water treatment and desalination. Sci Total Environ 2019; 646:1126-1139.
  16. Rajabi M, Mahanpoor K, Moradi O. Removal of dye molecules from aqueous solution by carbon nanotubes and carbon nanotube functional groups: Critical review. RSC Adv 2017; 7(74):47083-47090.
  17. Su Z, Wang H, Ye X, Tian K, Huang W, He J, Guo Y, Tian X. Anisotropic thermally conductive flexible polymer composites filled with hexagonal born nitride (h-BN) platelets and ammine carbon nanotubes (CNT-NH2): Effects of the filler distribution and orientation. Compos Part A: Appl Sci Manuf 2018; 109:402-412.
  18. Beigmoradi R, Samimi A, Mohebbi-Kalhori D. Engineering of oriented carbon nanotubes in composite materials. Beilstein J Nanotechnol 2018; 9(1):415.
  19. Cob J, Oliva-Avilés A, Avilés F, Oliva A. Influence of concentration, length and orientation of multiwall carbon nanotubes on the electromechanical response of polymer nanocomposites. Mater Res Express 2019; 6(11):115024.
  20. Razib MABM, Saleh T. A review on micro-patterning processes of vertically aligned carbon nanotubes array (VACNTs array). Curr Nanosci 2019; 15(4):328-353.
  21. Xie XL, Mai YW, Zhou XP. Dispersion and alignment of carbon nanotubes in polymer matrix: A Mater Sci Eng R: Reports 2005; 49(4):89-112.
  22. Iakoubovskii K. Techniques of aligning carbon nanotubes. Cent Eur J Phys 2009; 7(4):645-653.
  23. Li L, Yang Z, Gao H, Zhang H, Ren J, Sun X, Chen T, Kia HG, Peng H. Vertically aligned and penetrated carbon nanotube/polymer composite film and promising electronic applications. Adv Mater 2011; 23(32):3730-3735.
  24. Murugesh AK, Uthayanan A, Lekakou C. Electrophoresis and orientation of multiple wall carbon nanotubes in polymer solution. Appl Phys A 2010; 100(1):135-144.
  25. Singer G, Sinn G, Rennhofer H, Schuller R, Grünewald TA, Unterlasscd MM, Windberger U, Lichtenegger HC. High performance functional composites by in-situ orientation of carbon nanofillers. Compos Struct 2019; 215:178-184.
  26. Tran CD, Le-Cao K, Bui TT. Dielectrophoresis can control the density of CNT membranes as confirmed by experiment and dissipative particle simulation. Carbon 2019; 155:279-286.
  27. Beigmoradi R, Aghamiri F. The effects of suspending medium on dielectrophoretic systems for separating and sorting carbon nanotubes. J Particle Sci Technol 2019; 5(4):123-134.
  28. Romyen N, Thongyai S, Praserthdam P. Alignment of carbon nanotubes in polyimide under electric and magnetic fields. J Appl Polym Sci 2012; 123(6):3470-3475.
  29. Goh PS, Ismail AF, Ng BC. Directional alignment of carbon nanotubes in polymer matrices: Contemporary approaches and future advances. Compos Part A: Appl Sci Manuf 2014; 56: 103-126.
  30. Hu X, Sun J, Peng R, Tang Q, Luo Y, Yu P. Novel thin-film composite reverse osmosis membrane with superior water flux using parallel magnetic field induced magnetic multi-walled carbon nanotubes. J Clean Prod 2020; 242:118423.
  31. Walters DA, Casavant MJ, Qin XC, Huffman CB, Boul PJ, Ericson LM, Haroz EH, Connell MJO, Smith K, Colbert, DT, Smalley RE. In-plane-aligned membranes of carbon nanotubes. Chem Phys Lett 2001; 338(1):14-20.
  32. Liu M, Younes H, Hong H, Peterson G. Polymer nanocomposites with improved mechanical and thermal properties by magnetically aligned carbon nanotubes. Polym 2019; 166:81-87.
  33. Ciambella J, Stanier DC, Rahatekar SS. Magnetic alignment of short carbon fibres in curing composites. Compos Part B: Eng 2017; 109:129-137.
  34. Zarnegar Z, Safari J. The novel synthesis of magnetically chitosan/carbon nanotube composites and their catalytic applications. Int J Biolog Macromol 2015; 75:21-31.
  35. Ţucureanu V, Matei A, Avram AM. FTIR Spectroscopy for Carbon Family Study. Crit Rev Analyt Chem 2016; 46(6):502-520.
  36. Lin YT, Singh R, Kuo SW, Ko FH. Bio-Inspired Supramolecular Chemistry Provides Highly Concentrated Dispersions of Carbon Nanotubes in Polythiophene. Mater 2016; 9(6):438.
  37. do Amaral Montanheiro TL, Cristovan FH, Machado JPB, Tada DB, Duran N, Lemes AP. Effect of MWCNT functionalization on thermal and electrical properties of PHBV/MWCNT nanocomposites. J Mater Res 2015; 30(1):55-65.
  38. Wulandari S, Widiyandari H, Subagio A. Synthesis and characterization carboxyl functionalized Multi-Walled Carbon Nanotubes (MWCNT-COOH) and NH2 functionalized Multi-Walled Carbon Nanotubes (MWCNTNH2). J Phys Conf Series 2018; 1025(1):012005.
  39. Maleki A, Hamesadeghi U, Daraei H, Hayati B, Najafi F, McKay G, Rezaee R. Amine functionalized multi-walled carbon nanotubes: single and binary systems for high capacity dye removal. Chem Eng J 2017; 313:826-835.
  40. Ma PC, Siddiqui NA, Marom G, Kim JK. Dispersion and Functionalization of Carbon Nanotubes for Polymer-Based Nanocomposites: A Review. Compos Part A: Appl Sci Manufact 2010; 41(10):1345-1367.
  41. Zhao Z, Yang Z, Hu Y, Li J, Fan X. Multiple functionalization of multi-walled carbon nanotubes with carboxyl and amino groups. Appl Surf Sci 2013; 276:476-481.
  42. Shi D, He P, Zhao P, Guo FF, Wang F, Huth C, Chaud X, Bud’ko SL, Lian J. Magnetic alignment of Ni/Co-coated carbon nanotubes in polystyrene composites. Compos Part B: Eng 2011; 42(6):1532-1538.
  43. Yao Y, Xu F, Chen M, Xu Z, Zhu Z. Adsorption behavior of methylene blue on carbon nanotubes. Bioresource Technol 2010; 101(9):3040-3046.
  44. Farghali AA, Bahgat M, El Rouby WMA, Khedr MH. Decoration of MWCNTs with CoFe2O4 Nanoparticles for Methylene Blue Dye Adsorption. J Solut Chem 2012; 41(12):2209-2225.
  45. Ai L, Zhang C, Liao F, Wang Y, Li M, Meng L, Jiang J. Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: kinetic, isotherm and mechanism analysis. J Hazard Mater 2011; 198:282-290.
Journal of Advanced Materials in Engineering (Esteghlal)
Volume 42, Issue 1
June 2023
Pages 17-32

Files

Share

How to cite

Statistics

ارتقاء امنیت وب با وف ایرانی