Evaluation of the Electromagnetic Behavior of TiC/Ti3AlC2 Ceramic Matrix Composites Synthesized by in Situ Method

Document Type : Original Article

Authors

Department of Materials Science and Advanced Materials of Electromagnetics, Malek-Ashtar University of Technology (MUT), P.O.Box 83145/15, Shahin-Shahr, Isfahan, Iran

Abstract

The present research has aimed to investigate the effect of Ti3AlC2 reinforcing MAX phase on the electromagnetic behavior of TiC matrix composites. In this case, the milling process and secondary heat treatment were used for the synthesis of the composite. The resulting structures were examined by scanning electron microscope, differential thermal analysis, and X-ray diffractometer. Electromagnetic behavior was investigated by vector network analyzer. The investigations showed that it is possible to create a TiC/Ti3AlC2 composite structure in situ after milling. Electromagnetic investigations revealed that the electromagnetic absorption behavior of TiC/Ti3AlC2 ceramic matrix composite was improved compared to the original TiC. So that the lowest reflection loss of the milled composite was equal to -19.46 dB in the frequency range of 1 to 18 GHz band. After annealing at 1400 °C, it was found that the Ti3AlC2 phase resulting from the milling process was not stable and turned into the single phase solid solution of TiCx. Electromagnetic investigations of the annealed sample showed that after removing the MAX phase, the electromagnetic absorption behavior was weakened. Thus, the lowest reflection loss of the annealed sample was equal to -9.82 dB.

Keywords

Main Subjects

References

  1. Ghasemi A. Magnetic Ferrites and Related Nanocomposites: Elsevier; 2022.
  2. Han M-G. Electromagnetic Materials and Devices: Intech Open; 2020.
  3. Joseph K, Wilson R, Gejo G. Materials for potential EMI shielding applications: processing, properties and current trends: Elsevier; 2019.
  4. Baviera P, Harel S, Garem H, Grosbras M. Elaboration and structure of anostructured TiC: a XRD and HRTEM study. Journal of Scripta Materialia 2001;44(12):2721-7.
  5. Jia H, Zhang Z, Qi Z, Liu G, Bian X. Formation of nanocrystalline TiC from titanium and different carbon sources by mechanical alloying. Journal of Alloys and Compounds 2009;472(1-2):97-103.
  6. Wang Y, Luo F, Zhou W, Zhu D. Dielectric and electromagnetic wave absorbing properties of TiC/epoxy composites in the GHz range. Journal of Ceramics International 2014;40(7):10749-54.
  7. Liu Y, Li Y, Luo F, Su X, Xu J, Wang J, Qu Y, Yimin S. Mechanical, dielectric and microwave absorption properties of TiC/cordierite composite ceramics. Journal of Materials Science: Materials in Electronics 2017;28:12115-21.
  8. Shao T, Ma H, Wang J, Feng M, Yan M, Wang J, Yang Z, Zhou Q, Luo H, Qu S. High temperature absorbing coatings with excellent performance combined Al2O3 and TiC material. Journal of the European Ceramic Society 2020;40(5):2013-9.
  9. Zhang Z, Duan X, Jia D, Zhou Y, van der Zwaag S. On the formation mechanisms and properties of MAX phases: A review. Journal of the European Ceramic Society 2021;41(7):3851-78.
  10. Kumar JA, Prakash P, Krithiga T, Amarnath DJ, Premkumar J, Rajamohan N, Vasseghian Y, Saravanan P, Rajasimman M. Methods of synthesis, characteristics, and environmental applications of Mxene: A comprehensive review. Journal of Chemosphere 2022;286(1):131607-12.
  11. Sokol M, Natu V, Kota S, Barsoum MW. On the chemical diversity of the MAX phases. Trends in Chemistry 2019;1(2):210-23.
  12. Yao P, Li X, Zhang Y, Ma K, Zhang X, Li M, Zuo J, Li T, Lin L, Li C, Xu J. Electromagnetic Wave Absorption and Shielding Performances and Mechanisms of a Porous Ti3AlC2/SiC Gradient Composite. Journal of ACS Applied Electronic Materials 2023;5(3):1558-65.
  13. Guo Y, Guo X, Jian X. High-temperature stability core-shell engineered Ti3AlC2@C@SiO2 for excellent microwave absorbing properties. Journal of Vacuum 2023;212(1):112049-52
  14. Mao F, Long L, Pi W, Li Y, Zhou W. X-band electromagnetic absorption and mechanical properties of mullite/Ti3AlC2 Journal of Materials Chemistry and Physics 2022;292(1):126819-25.
  15. Liu Y, Luo F, Su J, Zhou W, Zhu D, Li Z. Enhanced mechanical, dielectric and microwave absorption properties of cordierite based ceramics by adding Ti3SiC2 Journal of Alloys and Compounds 2015;619(1):854-60.
  16. Bandyopadhyay D, Sharma R, Chakraborti N. The Ti-Al-C system (titanium-aluminum-carbon). Journal of phase equilibria 2000;21(2):195-8.
  17. Pang WK, Low I-M, O'connor B, Studer AJ, Peterson V, Sun Z, Palmquist J. Comparison of thermal stability in MAX 211 and 312 phases. Journal of Physics: Conference Series 2010;251(1):12025-32.
  18. Yao L, Zhu C-C, Jiang J-X, Zhou B-B. Mechanical properties of Ti3AlC2 ceramics before and after heat treatment. Journal of Rare Metals 2015;1(1):1-6.
  19. Yoshida M. Microstructural examination during the formation of Ti3AlC2 from mixtures of Ti/Al/C and Ti/Al/TiC. Advances in Science and Technology of Mn+1AXn Phases: Journal of Advances in Science and Technology of Mn+1AXn Phases 2012;1(1):81-101.
  20. Zou Y, Sun Z, Tada S, Hashimoto H. Synthesis reactions for Ti3AlC2 through pulse discharge sintering Ti/Al4C3/TiC powder mixture. Journal of Scripta materialia 2006;55(9):767-70.
  21. Dai B, Zhao B, Xie X, Su T, Fan B, Zhang R, Yang R. Novel two-dimensional Ti3C2Tx MXenes/nano-carbon sphere hybrids for high-performance microwave absorption. Journal of Materials Chemistry C 2018;6(21):5690-7.
  22. Tong XC. Advanced materials and design for electromagnetic interference shielding: CRC press; 2016.
  23. Wang C, Han X, Xu P, Zhang X, Du Y, Hu S, Wang J Wang X. The electromagnetic property of chemically reduced graphene oxide and its application as microwave absorbing material. Journal of Applied Physics Letters 2011;98(7):72906-12.
  24. Chen N, Yang K, Gu M. Microwave absorption properties of La-substituted M-type strontium ferrites. Journal of Alloys and Compounds 2010;490(2):609-12.
  25. Koo CM, Sambyal P, Iqbal A, Shahzad F, Hong J. Two-Dimensional Materials for Electromagnetic Shielding: John Wiley & Sons; 2021.
  26. Marka SK, Sindam B, Raju KJ, Srikanth VV. Flexible few-layered graphene/poly vinyl alcohol composite sheets: synthesis, characterization and EMI shielding in X-band through the absorption mechanism. Journal of RSC Advances 2015;5(46):36498-506.
  27. Liang J, Wang Y, Huang Y, Ma Y, Liu Z, Cai J, Zhang C, Gao H Chen Y. Electromagnetic interference shielding of graphene/epoxy composites. Journal of Carbon 2009;47(3):922-5.
  28. Zhu C-L, Zhang M-L, Qiao Y-J, Xiao G, Zhang F, Chen Y-J. Fe3O4/TiO2 core/shell nanotubes: synthesis and magnetic and electromagnetic wave absorption characteristics. The Journal of Physical Chemistry C 2010;114(39):16229-35.
  29. Wen Q, Zhou W, Wang Y, Qing Y, Luo F, Zhu D, Huang Z. Enhanced microwave absorption of plasma-sprayed Ti3SiC2/glass composite coatings. Journal of Materials Science 2017;52(1):832-4.
Journal of Advanced Materials in Engineering (Esteghlal)
Volume 42, Issue 1
June 2023
Pages 33-44

Files

Share

How to cite

Statistics

ارتقاء امنیت وب با وف ایرانی