عملکرد الکتروشیمیایی کاتد لیتیوم وانادیوم فسفات سنتزشده به روش احتراق محلولی با کمک ستیل تری متیل آمونیوم بروماید به‌عنوان سوخت جهت کاربرد در باتری‌های لیتیوم- یون

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشکده مهندسی مواد و متالورژی دانشگاه علم و صنعت ایران، تهران، ایران

چکیده

مقدمه و اهداف: بهینه‌سازی فسفات‌های قلیایی وانادیوم از طریق کنترل روش‌های سنتز، نقش کلیدی در بهبود عملکرد آن‌ها ایفا می‌کند. در این پژوهش، تأثیر افزودن سوخت ستیل تری متیل آمونیوم بروماید با درصدهای مولی مختلف نسبت ماده اکسنده (نیترات لیتیوم) برخواص الکتروشیمیایی کاتد لیتیوم وانادیوم فسفات بررسی شد.
مواد و روش‌ها: روش سنتز احتراقی محلول، برای تولید نمونه‌های لیتیوم وانادیوم فسفات با دو نسبت مختلف سوخت به اکسنده (0/5= φ و 1=φ) استفاده گردید و از ستیل تری متیل آمونیوم بروماید علاوه بر سوخت به‌عنوان منبع کربن نیز استفاده شد.
یافته‌ها: نتایج میکروسکوپ الکترونی روبشی نشان داد که افزایش نسبت سوخت به اکسنده از 0/5 به 1، باعث ایجاد ذرات کروی در مورفولوژی شد که به نوبه خود منجر به بهبود عملکرد الکتروشیمیایی شد. نمونه لیتیوم وانادیوم فسفات با 1=φ ، عملکرد الکتروشیمیایی برتر با ظرفیت تخلیه ویژه‌ای معادل 111/17 میلی‌آمپر ساعت بر گرم در نرخ جریان  C 0/1 و 68 میلی‌آمپر ساعت بر گرم در نرخ جریان C 5 از خود نشان داد. پس از 150 چرخه، نمونه نمونة لیتیوم وانادیوم فسفات با 1=φ  ظرفیت 79/16 میلی‌آمپر ساعت بر گرم را در نرخ جریان C 5 حفظ کرد.
نتیجه‌گیری: یافته های این پژوهش نشان میدهد که استفاده از ستیل تری متیل آمونیوم بروماید در فرایند سنتز احتراقی محلول و تنظیم نسبت سوخت به اکسنده، می‌تواند نقش مهمی در بهینه‌سازی ساختار و بهبود عملکرد الکتروشیمیایی کاتد لیتیوم وانادیوم فسفات داشته باشد. نتایج این تحقیق می‌تواند در بهینه‌سازی فرایندهای سنتز و توسعه مواد جدید برای باتری‌های نسل بعدی مورد استفاده قرار گیرد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Investigating the Electrochemical Characteristics of Lithium Vanadium Phosphate Cathode Synthesized by the Solution Combustion Method Utilizing Cetyltrimethylammonium Bromide as a Fuel for Lithium-Ion Batteries Applications

نویسندگان [English]

  • Mohammad Tahernejad Javazm
  • Masoud Hasheminiasari
  • Seyed Morteza Masoudpanah
Department of Materials Science and Engineering, Iran University of Science and Technology, Tehran, Iran
چکیده [English]

Introduction and Objectives: Optimization of vanadium phosphate compounds through the control of synthesis methods plays a key role in enhancing their performance. In this research, the effect of adding cetyltrimethylammonium bromide with different molar percentages relative to the oxidizer (lithium nitrate) on the electrochemical properties of lithium vanadium phosphate cathode was investigated.
Materials and Methods: The solution combustion synthesis method was used to produce lithium vanadium phosphate samples with two different fuel-to-oxidizer ratios (φ = 0.5 and φ = 1). Cetyltrimethylammonium bromide was used not only as a fuel but also as a carbon source.
Results: Scanning electron microscopy results showed that increasing the fuel-to-oxidizer ratio from 0.5 to 1 led to the formation of spherical particles in the morphology, which improved the electrochemical performance. The lithium vanadium phosphate sample with φ = 1 exhibited superior electrochemical performance, with a specific discharge capacity of 111.17 mAh/g at a current rate of 0.1C and 68 mAh/g at a current rate of 5C. After 150 cycles, the lithium vanadium phosphate sample with φ = 1 maintained a capacity of 79.16 mAh/g at a current rate of 5C.
Conclusion: The findings of this research indicate that the use of cetyltrimethylammonium bromide in the solution combustion synthesis process and the adjustment of the fuel-to-oxidizer ratio can play a significant role in optimizing the structure and improving the electrochemical performance of lithium vanadium phosphate cathode. The results of this study can be utilized in optimizing synthesis processes and developing new materials for next-generation batteries.

کلیدواژه‌ها [English]

  • Fuel-to-oxidant ratio
  • Li3V2(PO4)3
  • Discharge capacity
  • Cycling performance
  • Rate capability
  • Kinetic properties
  • Solution combustion synthesis

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مواد پیشرفته در مهندسی
دوره 44، شماره 3
(شماره پیاپی 50)
مهر 1404
صفحه 101-114

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