بررسی اثر طول موج لیزر و محیط بر سنتز نانوذرات مس و اکسید مس با لیزر YAG:Nd نانوثانیه در مایع

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه صنعتی مالک اشتر، مجتمع دانشگاهی مواد و فناوری‌های ساخت

چکیده

در این تحقیق نانوذرات مس با استفاده از روش فرسایش لیزری در مایع با استفاده از لیزر Nd:YAG نانوثانیه سنتز شدند. ابتدا اثر طول‌موج‌های 532 نانومتر و 1064 نانومتر بر سنتز نانوذرات مس در محیط‌های آب مقطر و استون مورد بررسی قرار گرفت. پس از یافتن طول‌موج مناسب، اثر محیط‌های سنتز در حضور سورفکتانت‌های ستیل تری‌متیل آمونیوم کلرید، سدیم دودسیل سولفات و پلی‌وینیل پیرولیدون روی نانوذرات مس مورد بررسی قرار گرفت. برای بررسی خواص نوری، بازده سنتز، اندازه و مورفولوژی نانوذرات مس تهیه شده به روش فرسایش لیزری در مایع به‌ترتیب از آنالیزهای طیف‌سنجی نوری مرئی– فرابنفش، طیف‌سنجی جذب اتمی، پراش نور دینامیکی و میکروسکوپ الکترونی روبشی گسیل میدانی استفاده شد. نتایج نشان داد که نانوذرات مس را می‌توان با موفقیت در محیط استون در طول‌موج 1064 نانومتر سنتز کرد. همچنین، به دلیل تشکیل اکسیدهای مس به‌جای نانوذرات مس، احتمال کمی برای تهیه نانوذرات مس در محیط‌های آبی وجود دارد. 

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Investigating the Effect of Laser Wavelength and Environment on the Synthesis of Copper and Copper Oxide Nanoparticles by Nanosecond Nd:YAG Laser in Liquid

نویسندگان [English]

  • H. Naderi-Samani
  • R. Shoja Razavi
  • R. Mozaffarinia
Faculty of Materials and Manufacturing Technologies, Malek Ashtar University of Technology, Iran
چکیده [English]

In this research, copper nanoparticles were synthesized via laser ablation in liquid using a nanosecond Nd:YAG laser. First, the effect of wavelengths of 532 nm and 1064 nm on the synthesis of copper nanoparticles in acetone and distilled water was investigated. After finding the appropriate wavelength, the effect of synthesis media in the presence of surfactants containing cetyltrimethylammonium chloride, sodium dodecyl sulfate, and polyvinyl pyrrolidone on copper nanoparticles was studied. Visible-ultraviolet optical spectroscopy, atomic absorption spectroscopy, dynamic light diffraction, and field emission scanning electron microscopy were employed to investigate the optical properties, synthesis efficiency, size, and morphology of copper nanoparticles prepared by the laser ablation in liquid method, respectively. The results showed that copper nanoparticles could be successfully synthesized in an acetone medium at 1064 nm wavelength. Also, due to the formation of copper oxides instead of copper nanoparticles, there is a slight possibility of preparing copper nanoparticles in aqueous environments.

کلیدواژه‌ها [English]

  • Copper nanoparticles
  • Copper oxide
  • Laser ablation
  • Colloid containing nanoparticles

مراجع

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مواد پیشرفته در مهندسی
دوره 43، شماره 1
خرداد 1403
صفحه 27-39

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