رسوب‌دهی الکتریکی و مشخصه‌یابی پوشش‌های نانوبلوری آلیاژ نیکل- مولیبدن

نویسندگان

دانشکده مهندسی مواد، دانشگاه صنعتی اصفهان

چکیده

در این پژوهش پوشش‌های نانوبلوری آلیاژ نیکل- مولیبدن به‌روش رسوب‌دهی الکتریکی و از حمام سیترات – آمونیاکی، با اعمال چگالی جریان‌های 30، 60 و mA/cm2 100 بر روی زیر لایه فولادی ایجاد شدند. نتایج نشان داد که پوشش‌های ایجاد شده یکنواخت و فشرده هستند و افزون بر آن با افزایش چگالی جریان پوشش‌دهی، مقدار مولیبدن آلیاژ و بازده جریان کاهش پیدا می‌کنند. تحلیل پراش پرتو ایکس نشان داد که تمامی پوشش‌ها، محلول جامدی از مولیبدن در نیکل و با اندازه دانه 5- 9 نانومتر بودند. هم‌چنین صفحه بلوری (111) برای نیکل بیشترین شدت در طیف پراش پرتو ایکس را داشت. بررسی زبری پوشش‌های به‌دست آمده نشان داد که با افزایش چگالی، زبری این پوشش‌ها افزایش یافته است. بررسی رفتار خوردگی گویای کاهش چگالی جریان خوردگی زیرلایه با اعمال پوشش‌های آلیاژی نیکل- مولیبدن بود. افزون بر این با افزایش مقدار مولیبدن پوشش، چگالی جریان خوردگی کاهش یافت که کمترین مقدار مربوط به پوشش با مقدار 13 درصد اتمی مولیبدن بود.

کلیدواژه‌ها

عنوان مقاله [English]

Electrodeposition and Characterization of Nanocrystalline Nickel- Molybdenum Alloy

نویسندگان [English]

  • V. Rajaei
  • K. Raeissi
  • M. Shamanian
  • H. Rashtchi
Department of Materials Engineering, Isfahan University of Technology, Isfahan, Iran
چکیده [English]

In this study, Ni-Mo nanocrystalline alloys were prepared on steel substrates by electrodeposition method from citrate-ammonia bath by applying current densities 30, 60 and 100 mA/cm2. Results indicated that the obtained coatings were uniform and compact. Moreover, molybdenum content in the alloy and current efficiency decreased with increasing electrodeposition current density. X-ray diffraction analyses indicated that all coatings were composed of face-centered cubic solid solution of molybdenum in nickel with grain size of 9-5 nanometer. Moreover, the most intensive plane in X-ray diffragtogram was (111). On the othe hand, roughness measurements indicated that surface roughness escalated with increasing current density. Corrosion behavior study showed decrease in corrosion current density of substrate with applying Ni-Mo alloy coatings. In addition, corrosion current density reduced with increasing molybdenum content of the coating and the minimum amount was related to the coating with 13 atomic percent molybdenum.

کلیدواژه‌ها [English]

  • Nickel- Molybdenum Alloy
  • electrodeposition
  • morphology
  • current density

مراجع

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مواد پیشرفته در مهندسی
دوره 35، شماره 1
خرداد 1395
صفحه 71-81

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