اثر افزودن بور بر ساختار، سختی و دماهای استحاله آلیاژ حافظه‌دار Cu-12Al-4Ni تهیه شده به روش آلیاژسازی مکانیکی، پرس و نورد

نویسندگان

1 1. دانشکده مهندسی مواد و متالورژی، پردیس دانشکده‌های فنی، دانشگاه تهران

2 2. گروه مهندسی متالورژی و مواد، دانشگاه صنعتی همدان

چکیده

در این پژوهش، ساخت آلیاژ حافظه‌دار Cu-12wt%Al-4wt%Ni حاوی بور به‌روش آلیاژسازی مکانیکی، پرس و نورد مورد بررسی قرار گرفت. برای تهیه نمونه بالک از پودرهای آلیاژسازی مکانیکی شده به‌مدت 20 و 40 ساعت، از روش‌های پرس سرد، تف­جوشی، نورد، عملیات حرارتی و کوئنچ استفاده شد. ساختار فازی، میکروساختار، میکروسختی و دمای استحاله نمونه‌های حاصل مورد مطالعه قرار گرفت. مشخص شد که با افزایش زمان آسیاکاری از 20 به 40 ساعت دماهای شروع استحاله مارتنزیتی از 254 به 264 درجه سانتی‌گراد افزایش پیدا می‌کند. همچنین، نتایج نشان داد که افزودن عنصر بور به مقدار 5/0 درصد وزنی باعث افت دمای استحاله به 211 درجه سانتی‌گراد و افزایش میکروسختی از مقدار 154 به 193 ویکرز می‌شود که علت آن به ریزدانه شدن در اثر ظهور رسوبات غنی از بور نسبت داده شد. به‌دلیل ناهمگنی نسبی در غلظت آلومینیوم در زمینه و تشکیل مارتنزیت با ساختار متفاوت، استحاله دو مرحله‌ای بروز کرد که در نمودار آزمون گرماسنجی تفاضلی روبشی  DSCبه‌صورت دو پیک مجزا ظاهر شد.

کلیدواژه‌ها

عنوان مقاله [English]

The Effect of Boron Addition on the Microstructure, Hardness and Characteristic Temperatures of Cu-12Al-4Ni Memory Alloy Prepared by Mechanical Alloying, Pressing and Rolling

نویسندگان [English]

  • Z. Jarrahi 1
  • Sh. Raygan 1
  • M. Pourabdoli 2
1 1. Department of Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
2 2. Department of Materials Engineering, Hamedan University of Technology, Hamedan, Iran.
چکیده [English]

In this study, boron containing Cu-12wt%Al-4wt%Ni shape memory alloy was prepared by mechanical alloying, pressing and rolling. In this regard, 20 and 40 hour-milled powder was compacted and changed to the bulk alloy by cold pressing, sintering, rolling, heat treatment and quenching. Phase structure, micro-structure, micro-hardness, and transformation temperatures of the prepared samples were studied. It was found that increasing the milling time from 20 to 40 hours led to the rise of the starting temperature of martensite transformation (Ms) from 254 to 264°C. Also, the results showed that adding 0.5 wt.% B decreased the Ms temperature to 211°C and enhanced the micro-hardness from 154 (for the sample without B) to 193  vickers. These alternations were attributed to the fine structure caused by Boron rich precipitations. Moreover, two martenistic transformations with different structures were formed due to the non-homogeneity of the Al concentration in the matrix, which appeared in the form of two different transformation temperatures (Ms) in the Differential Scanning Calorimetry curves.

کلیدواژه‌ها [English]

  • Shape memory alloy
  • Cu-12Al-4Ni
  • Phase transformation temperature
  • Boron
  • Differential Scanning Calorimetry

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مواد پیشرفته در مهندسی
دوره 37، شماره 4
اسفند 1397
صفحه 59-72

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